Isolation and Characterization of the Free Phenylphosphinidene Chalcogenides C 6 H 5 P=O and C 6 H 5 P=S, the Phosphorous Analogues of Nitrosobenzene and Thionitrosobenzene
نویسندگان
چکیده
منابع مشابه
Heats of formation of C(6)H(5)(•), C(6)H(5)(+), and C(6)H(5)NO by threshold photoelectron photoion coincidence and active thermochemical tables analysis.
Threshold photoelectron photoion coincidence has been used to prepare selected internal energy distributions of nitrosobenzene ions [C(6)H(5)NO(+)]. Dissociation to C(6)H(5)(+) + NO products was measured over a range of internal energies and rate constants from 10(3) to 10(7) s(-1) and fitted with the statistical theory of unimolecular decay. A 0 K dissociative photoionization onset energy of 1...
متن کاملDinitrogen addition to c - C 5 H 5 Fe + , C 6 H 6 Fe + and FeO + in the gas phase
Results of an experimental study using the selection-ion flow tube technique are reported for reactions of bare Fe + and iron containing FeX ÷ cations (X = C6H 6 (or B), c-C5n 5 (or Cp), O, (Cp)2, B 2) with dinitrogen at 294 _+ 3 K and at a helium buffer-gas pressure of 0.35 _+ 0.01 Torr. Fe z, B2Fe + and Cp2Fe + do not react with dinitrogen. A very slow sequential addition of two N z molecules...
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چکیده ندارد.
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ژورنال
عنوان ژورنال: Angewandte Chemie International Edition
سال: 2020
ISSN: 1433-7851,1521-3773
DOI: 10.1002/anie.202004172